(S)-T-BINAP

Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, BINAPs

(S)-T-BINAP is a versatile chiral organophosphorus ligand and has been used in several catalytic applications such as:

1. Palladium catalyzed carbon-oxygen bond formation (Ref: J. Am. Chem. Soc., 1997, 119, 11108)

2. Palladium-catalyzed α-arylation reaction of ketones (Ref: J. Am. Chem. Soc., 2000, 122, 6797)

3. Cu-catalyzed asymmetric conjugate reduction (Ref: J. Am. Chem. Soc., 1998, 120, 837)

4. Cu-catalyzed asymmetric dienolate addition to aldehydes (Ref: J. Am. Chem. Soc., 2003, 125, 11253)

5. Enantioselective conjugate reduction of lactones and lactams (Ref: Org. Lett., 2003, 5(20), 3691)

6. Enantioselective cycloaddition of allenylsilanes with α-Imino esters (Ref: J. Am. Chem. Soc., 2003, 125, 5644)

7. Catalytic Aldol reaction to ketones (Ref: Org. Lett., 2005, 7(22), 4955)

8. Rhodium catalyzed [2+2+2] cycloaddition reaction of alkenes and alkynes (Org. Lett., 2011, 13, 4692)

9. Iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes (Ref: J. Am. Chem. Soc., 2014, 136, 8911)

10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols (Ref: J. Am. Chem. Soc., 2014, 136, 8911)

11. Rhodium-catalyzed cross cyclotrimerization (Angew. Chem., Int. Ed., 2014, 53, 2956)

Note: Please check notes for S-BINAP for additional applications

CAS Number

#100165-88-6

Synonyms

(S)-(−)-2,2′-p-tolyl-phosphino)-1,1′-binaphthyl, (S)-Tol-BINAP

Molecular Formula

C₄₈H₄₀P₂

MDL Number

MFCD01311709

Chemical Name

(S)-T- BINAP

Molecular Weight

678.78

Melting Point

250-255 °C

Purity

Above 99%

Packaging

1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.

Color

White

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