[Rh((S)-T-BINAP)2]BF4

[Rh((S)-T-BINAP)2]BF4

Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, BINAPs, Rh Catalysts

Applications:

[Rh((S)-T-BINAP)2]BF4 is a chiral hydrogenation and isomerization catalyst

Ref:

1)J. Org. Chem. 1998, 63, 428

2) Acta Chemica Scandinavica, 1996, 50, 353

Applications : Asymmetric synthesis; as a varient to Asymmetric Isomerization of Allylamines (Angew. Chem. Int. Ed. Engl., 1985, 24, 217); Asymmetric Hydrogenation of a-(Acylamino)acrylic Acids (J. Am. Chem. SOC., 1980, 102, 7932)