Chiral Catalysts, Ligands, Reagents, Privileged Ligands and Complexes, Asymmetric Synthesis, Chemical Synthesis, and BINAPs
(R)-Ru(OAc)2(BINAP) can be used for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins.
ref: BINAP-Ru (II) and BINAP-Rh (I)-catalyzed asymmetric hydrogenation of olefins without heteroatom-functionalities Ohta T, et al. Journal of Organometallic Chemistry 502(1-2), 169-176, (1995)
(R)-Ru(OAc)2(BINAP) can also be used to catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.
Ref: Preparation of optically active 2-(trifluoromethyl) alkan-1-ols by catalytic asymmetric hydrogenation. Iseki K, et al. Journal of Fluorine Chemistry 69(1), 5-6, (1994)
Quantity | Availability | *Price (INR) |
---|---|---|
1 gm | In Stock | On Request |
10 gm | In Stock | On Request |
50 gm | In Stock | On Request |
1 kg | 4-5 Weeks | On Request |
25 kg | 8-10 Weeks (Negotiable) | On Request |
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