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Chiral Catalysts, Ligands, Reagents, Privileged Ligands and Complexes, Asymmetric Synthesis, Chemical Synthesis, and BINAPs

(R)-Ru(OAc)2(BINAP) can be used for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins.

ref: BINAP-Ru (II) and BINAP-Rh (I)-catalyzed asymmetric hydrogenation of olefins without heteroatom-functionalities Ohta T, et al. Journal of Organometallic Chemistry 502(1-2), 169-176, (1995)

(R)-Ru(OAc)2(BINAP) can also be used to catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.

Ref: Preparation of optically active 2-(trifluoromethyl) alkan-1-ols by catalytic asymmetric hydrogenation. Iseki K, et al. Journal of Fluorine Chemistry 69(1), 5-6, (1994)

CAS Number
Diacetato[(R)-(+)-2,2-bis(diphenylphosphino)-1,1−binaphthyl]ruthenium(II); Ru[(R)-BINAP](OCOCH3)2
Molecular Formula
MDL Number
Chemical Name
Molecular Weight
Melting Point
1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.
Light yellow

Price and Availability

QuantityAvailability*Price (INR)
1 gmIn StockOn Request
10 gmIn StockOn Request
50 gmIn StockOn Request
1 kg4-5 WeeksOn Request
25 kg8-10 Weeks (Negotiable)On Request

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(R)-Ru(OAc)2(BINAP) | Synthesis with Catalysts


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