Bis(triphenylphosphine)palladium(II) dichloride

Applications:

Bis(triphenylphosphine)palladium(II) dichloride can be used as a catalyst in:

1) Carbonylative cyclization of malonate derivatives (Ref: J. Am. Chem. Soc., 1989, 111, 8018; Tetrahedron Lett., 1990, 31, 2841)

2) Double allylation of activated olefins (Ref: J. Am. Chem. Soc., 1997, 119, 8113)

3) Preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans (Ref: J. Org. Chem., 2001, 66, 175)

4) Homocoupling of terminal alkynes (Ref: J. Org. Chem., 2002, 67, 1969)

5) Cross-coupling of alkynylsilanols and aryl halides (Ref: J. Org. Chem., 2003, 68, 9151)

6) Alkynylation of N-fused heterocycles (Ref: J. Am. Chem. Soc., 2007, 129, 7742)

7) Arylation of tautomerizable heterocycles (Ref: Angew. Chem. Int. Ed., 2008, 47, 4711)

8) Tandem Heck reaction/C-H functionalization (Ref: J. Am. Chem. Soc., 2008, 130, 11300)

CAS Number

#13965-03-2

Synonyms

trans-Dichlorobis(triphenylphosphine)palladium(II)

Molecular Formula

C₃₆H₃₀Cl₂P₂Pd

EC Number

237-744-2

MDL Number

MFCD00009593

Chemical Name

Bis(triphenylphosphine)palladium(II) dichloride

Molecular Weight

701.9

Packaging

1 gm, 10 Gm & 50 gm in Glass Bottles, Bigger packaging available on request.

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